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[apo_BCAA_dehydrogenase_E2_protein]_N6-dihydrolipoyl-L-lysine + NAD+ <=> [apo_BCAA_dehydrogenase_E2_protein]_N6-lipoyl-L-lysine + NADH + H+
|
1.8.1.4
dihydrolipoyl dehydrogenase
|
–
|
|
MetaCyc:
RXN-7719
|
|
|
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isobutyryl-CoA + [apo_BCAA_dehydrogenase_E2_protein]_N6-dihydrolipoyl-L-lysine <=> [apo_BCAA_dehydrogenase_E2_protein]_N6-S-[2-methylpropanoyl]dihydrolipoyl-L-lysine + CoA
|
2.3.1.168
dihydrolipoyllysine-residue (2-methylpropanoyl)transferase
|
–
|
|
MetaCyc:
2.3.1.168-RXN
|
|
|
|
2-oxoisovalerate + [apo_BCAA_dehydrogenase_E2_protein]_N6-lipoyl-L-lysine + H+ <=> [apo_BCAA_dehydrogenase_E2_protein]_N6-S-[2-methylpropanoyl]dihydrolipoyl-L-lysine + CO2
|
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
|
–
|
|
MetaCyc:
1.2.4.4-RXN
|
|